The inhibiting effect of cationic surfactant N, N, N‐dimethyl 4‐methylbenzyl dodecyl ammonium chloride on mild steel in hydrochloric acid solutions was investigated by surface and thermodynamic measurements, weight loss tests, polarization measurements and EDS techniques. The data obtained from surface and thermodynamic measurements with the inhibitor indicate that the area per molecule slightly increases with increasing temperature and both absorption and micellization processes are spontaneous. Weight loss measurement showed that the inhibition efficiencies increased with increasing surfactant concentration and attained a maximum around their critical micelle concentration. Polarization studies reveal that the inhibitor behaves as a mixed type in hydrochloric acid solutions and acted on the cathodic reaction without modifying the mechanism of the hydrogen evolution reaction. EDS measurement showed high coverage of surfactant on the mild steel surface.
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1 October 1998
Editors
Technical Paper|
October 01 1998
New cationic surfactant as corrosion inhibitor for mild steel in hydrochloric acid solutions Available to Purchase
Z. Abdel Hamid;
Z. Abdel Hamid
Central Metallurgical Research and Development Institute, Cairo, Egypt
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T.Y. Soror;
T.Y. Soror
Faculty of Science, Cairo University, Cairo, Egypt
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H.A. El‐Dahan;
H.A. El‐Dahan
National Research Center, Cairo, Egypt
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A.M.A. Omar
A.M.A. Omar
Egyptian Petroleum Research Institute, Cairo, Egypt
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Publisher: Emerald Publishing
Online ISSN: 1758-4221
Print ISSN: 0003-5599
© MCB UP Limited
1998
Anti-Corrosion Methods and Materials (1998) 45 (5): 306–311.
Citation
Abdel Hamid Z, Soror T, El‐Dahan H, Omar A (1998), "New cationic surfactant as corrosion inhibitor for mild steel in hydrochloric acid solutions". Anti-Corrosion Methods and Materials, Vol. 45 No. 5 pp. 306–311, doi: https://doi.org/10.1108/00035599810234605
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