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Purpose

To study the effects of isomers of organic compounds such as phenylenediamine, toluidine and nitroaniline as inhibitors for the corrosion of carbon steel in sulfuric acid.

Design/methodology/approach

Standard methods have been adopted in this study such as weight loss, polarization tests, impedance measurements and hydrogen permeation studies to find out the corrosion behavior of carbon steel in sulfuric acid with and without inhibitors.

Findings

All the selected isomers inhibited the corrosion. The best performance was found in ortho‐phenylenediamine when compared with other inhibitors under study.

Originality/value

It clearly shows the effect of isomers of phenylenediamine, toluidine and nitroaniline. The method of study may be applicable to find out the performance of other isomers of organic compounds. As these isomers behave as good inhibitors in sulfuric acid, these may be tried as inhibitors in other acids. Hence, this study is useful to academics and researchers in the field of corrosion science and engineering.

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