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Purpose

The paper aims to examine the enrichment of Cu, and the type of attack occurring during the dissolution of Al‐3.84%Cu alloy in 0.5 M NaCl.

Design/methodology/approach

The approach is to use scanning electron microscopy (SEM) and energy dispersive X‐ray spectroscopy (EDX) and solution analyses using atomic absorption spectrophotometry.

Findings

Examination of the surface after five days of immersion showed that Cu clusters had concentrated around the edges of the specimens and two types of localized corrosion were evident, pitting corrosion and the intergranular attack, which were concentrated mainly around the Cu clusters and in the regions where a higher concentration of Cu was evident. After 80 days of immersion, the higher concentration of Cu was distributed over nearly the entire surface and its concentration differed from one site to another.

Originality/value

The analysis results of the study confirmed the mechanism of simultaneous dissolution.

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