Effects of trace elements Hf and Si on oxidation behavior of Co-Ni-Al-W-based superalloys at 900°C Available to Purchase

This study aims to control the oxidation resistance of Co-based deformed superalloys by adding trace elements Hf and Si.

The effects and mechanism of trace elements Hf and Si on the oxidation behavior of Co-Ni-Al-W-based forged superalloys were investigated by cyclic oxidation at 900°C.

The results show that the addition of trace elements Hf and Si does not affect the type of surface oxides of Co-Ni-based superalloys, and the oxidation layers of the alloys are TiO₂, spinel, Cr₂O₃, TaTiO₄, Al₂O₃ and TiN from outside to inside. However, the addition of elements can affect the activity of Cr and Ti elements; decrease the formation of TiO₂ and TaTiO₄ layers, which are harmful to the oxidation performance; and then improve the oxidation resistance of the alloy.

The relevant research results can not only optimize the microalloying element content of Co-Ni-Al-W-based superalloys, but also provide a new perspective for the composition optimization design of superalloys.