The structure and protective effect of Al-coated Nd-Fe-B magnets before and after grain boundary diffusion were studied to explore the feasibility of improving the corrosion resistance of Nd-Fe-B magnets by Al coating and Al grain boundary diffusion.
The Al coating was deposited on sintered Nd-Fe-B magnets by magnetron sputtering, and then the Al-coated Nd-Fe-B magnets were put into the vacuum tube furnace for grain boundary diffusion process. The influence of Al coating and grain boundary diffusion process on the corrosion resistance of Nd-Fe-B magnets was investigated using electrochemical tests.
Results showed that the Al coating thickness increases, the corrosion current density of Al-coated magnets first increases and then decreases with increasing coating time. The Al coating particles transform from small millet shaped particles to equiaxed polygonal particles, and finally to big millet shaped particles with increasing coating time. The diffusion temperature has little effect on the corrosion potential, and the corrosion current density of Al-diffused magnets after grain boundary diffusion is much higher than that of Al-coated magnets before grain boundary diffusion. The corrosion potential and corrosion current density of magnets first increase, and then decrease with increasing tempering temperature.
As for high intrinsic coercivity Nd-Fe-B magnets, Poor preparation of Al coatings can result in Al coatings lacking protective properties, and the Al coating should be used cautiously as the surface protective coating of magnets. Grain boundary diffusion leads to the disappearance of Al coating, and reduces the corrosion resistance of Nd-Fe-B magnets, while tempering treatment can improve the corrosion resistance of Al-diffused magnets.
