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This paper describes the numerical solutions of type‐IV shock‐on‐shock interactions in hypersonic thermochemical nonequilibrium air flows around blunt bodies. The Navier‐Stokes equation solver for a chemically reacting and vibrationally relaxing gas mixture was applied to the present problem, where the concepts of the Advection Upstream Splitting Method (AUSM) and the Lower‐Upper Symmetric Gauss‐Seidel (LU‐SGS) method were basically employed along with the two‐temperature thermochemical model of Park. The aerodynamic heating with or without the shock‐on‐shock interaction to a sphere and circular cylinders are simulated for a hypersonic nonequilibrium flow. The numerical results show that typical type‐IV shock‐on‐shock interaction pattern with a supersonic jet structure is also formed in a high‐enthalpy thermochemical nonequilibrium flow, and that the contribution of convective heat flux in the translational/rotational mode to the total heat flux is dominant. Furthermore, the inherent unsteadiness of nonequilibrium type‐IV shock‐on‐shock interaction flowfield is discussed briefly.

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