Tribological behaviors and molecular spectroscopic characterization of a lubricated piston ring/cylinder bore sliding contact under stepwise heating conditions

The frictional behavior of a Mo alloy‐coated piston ring sliding against cast iron cylinder bore was recorded as a function of temperature using a reciprocating tribotester and a fully formulated synthetic engine oil, with and without a friction modifier. It was observed that, as temperature increased in a stepwise mode, friction coefficients in the presence of MoDTC exhibited two local minimal values. Only one minimal friction coefficient value at 340–355 °C (μ = 0.065) was observed in the absence of MoDTC. Chemical characterization of worn tracks of the cylinder bore using reflected FTIR spectroscopy, Raman spectroscopy and ESCA, indicated that both the base stock and the tribological additives, ZDTP and MoDTC, experienced tribochemical reactions yielding MoO₃, MoS₂ and carbonaceous species as temperature ramped up stepwise. MoO₃ and MoS₂ reaction film formation are partially responsible for the local minimal friction coefficient found at the lower temperature and the ratio of the ordered carbon species accounts partially for the other local minimal friction coefficient found at the higher temperature.