This paper aims to investigate the preparation of Nano-Al2O3 lubricant, as well as the effect of surface modification of Al2O3 on friction and wear properties.
The chemical parameters such as the energy levels of the Highest Occupied Molecular Orbital, the Lowest Unoccupied Molecular Orbital and the Fukui indices of seven modifiers, including myristic acid myristyl ester, glycerol trioleate, acetyl monoethanolamine, docosanamide, Tween-60, dodecyl dihydroxyethyl amine oxide and sodium dodecyl sulfate (SDS), are calculated by using the Materials Studio software. Meanwhile, the adsorption energies of these seven modifiers on Al2O3 nanoparticles are also calculated. Based on the simulation results, SDS and Tween-60 were identified as the most effective surface modifiers. Modified lubricants were prepared with Al2O3 nanoparticles at varying concentrations (0.1–0.4 Wt.%). Their tribological properties, including the maximum nonseizure load (PB) and the coefficient of friction (COF), were evaluated using a four-ball wear tester. The worn surfaces were analyzed by scanning electron microscopy and three-dimensional profilometry.
The results indicate that SDS improves both the extreme pressure and anti-wear performance of the lubricant. The lubricant achieves optimal performance when combined with 1.0 Wt.% SDS and 0.2 Wt.% nano-Al2O3. At this combination, the value of PB reaches 209 N, and the value of COF is approximately 0.072. Compared to the unmodified Al2O3 lubricant with a COF of 0.086, this represents a 23% reduction in COF.
Modified Al2O3 lubricants demonstrate superior lubrication performance and effectively reduce the COF, providing valuable insights for the practical application of nanolubricants.
The peer review history for this article is available at: https://publons.com/publon/10.1108/ILT-09-2024-0353/
