This study aims to replace petroleum-based lubricating oils with sustainable biomaterials, addressing issues associated with existing alternatives, such as poor performance, high cost and limited availability.
The transformation of agricultural waste cardanol, a nonedible vegetable oil that is abundantly available, into green cardanyl acetate (CA) biolubricating ester oil. The potential of CA as a base stock for lubricants is validated by assessing its lubrication performance.
CA exhibited a higher viscosity index, flash point and thermal stability than commercially available mineral-based (CTL3, coal-to-liquid) and synthetic (PAO2, poly-alpha-olefin) lubricant base stocks. Moreover, CA exhibits excellent anticorrosivity properties as well as PAO2 and CTL3. The tribological properties of CA were evaluated, and the results show that CA exhibits a smaller average wear scar diameter (WSD) of 0.54 mm than that of PAO2 (0.85 mm) and CTL3 (0.90 mm). In extreme pressure tests, acylated CA demonstrated the highest last nonseizure load capacity at 510 N, outperforming commercial CTL3 (491 N) and PAO2 (412 N). All results demonstrate that CA displays an excellent series of base stock properties.
The novelty of this work lies in the utilization of renewable agricultural waste, cashew nut shell liquid, to produce a high-value biolubricant as an alternative to commercial fossil-based lubricants. The renewable nature, low cost, and large-scale availability of raw materials pave a new path for the production and application of biolubricants, showcasing the immense potential of converting agricultural waste into high-value products.
The peer review history for this article is available at: https://publons.com/publon/10.1108/ILT-03-2024-0064/
