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The hydration of ordinary Portland cement at room temperature was studied in the presence of silica fume. The silica fume content was 0, 5, 10, 15 and 20 wt% of the weight of cement for all mixtures. The mixtures were stirred in 100 ml deionised water for different time intervals up to 7 days. The filtered solutions were analysed for pH, silicon and calcium ions. Most of the calcium hydroxide released during the hydration of Portland cement had reacted with the silica fume within 7 days. The X-ray diffraction and scanning electron microscopy studies on the hydration products showed a considerable reduction in the amount of calcium hydroxide as a result of its reaction with silica fume. The optimum condition was obtained by the addition of 20% silica fume.

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