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Artificial ground freezing (AGF) is widely used in geotechnical engineering for soil stabilisation and groundwater control under complex geological conditions. This study introduces an innovative AGF system employing low-temperature liquid carbon dioxide (CO2) as a circulating refrigerant in a closed-loop configuration. Field experiments were conducted at a shield tunnel construction site (Line Z4) in Tianjin Binhai New Area, China, characterised primarily by silty clay, clayey silt, and silty sand strata. Comparative tests with a conventional brine-based AGF system demonstrated that the liquid carbon dioxide system achieved significantly faster cooling, stabilising refrigerant temperatures at ≈−43·8°C within 20 days, compared to −30·8°C after 30 days for the brine-based system. The carbon dioxide-based system exhibited higher cooling efficiency, evidenced by shorter latent heat plateaus and steeper soil temperature gradients. After 20 days, soil temperatures reached −25°C to −30°C using carbon dioxide, whereas the brine method achieved only −5°C to −15°C. In addition, the carbon dioxide system reduced the frozen wall closure time by nearly one-third and increased freezing wall formation rates by 40%–50%. These findings highlight liquid carbon dioxide as a sustainable and highly efficient refrigerant, offering significant potential for advancing AGF technologies in geotechnical engineering applications.

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