This study aims to develop polylactic acid (PLA)–based composite films with improved mechanical and barrier properties through incorporation of micro boron nitride (BN) and nano boron nitride (NBN). PLA-based films were produced using BN and NBN at varying concentrations (1%–10% (w/w)) and characterized in terms of physical (color and thickness), mechanical (tensile strength, elongation at break, and heat seal strength), barrier (water vapor transmission rate (WVTR)), antimicrobial, and morphological properties. ΔE and whiteness of the composite PLA films increased, while transparency decreased with increased BN and NBN concentrations. Compared with the control PLA films, the tensile strength of the 1% BN- or NBN-added films increased by 28% or 40%, respectively. Adding BN and NBN to the PLA matrix significantly reduced the WVTR (p ≤ 0.05). Antimicrobial activity against Staphylococcus aureus and Escherichia coli was not detected. Multivariate data analysis enabled discrimination of composite PLA films based on simultaneous evaluation of their specific film characteristics. This study reveals the ideal film formulation to produce boron nitride–incorporated composite PLA films with proper properties, holding potential to be used as an alternative biodegradable material for sustainable packaging of foods to replace petroleum-based materials.
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1 December 2025
Research Article|
October 15 2024
Composite PLA films incorporated with micro/nano boron nitride for sustainable food packaging Available to Purchase
Ilknur Ara
;
Ilknur Ara
Master’s student, Department of Food Engineering, Faculty of Engineering,
Sakarya University
, Sakarya, Turkiye
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Guliz Haskaraca
;
Guliz Haskaraca
Assistant Professor, Department of Food Engineering, Faculty of Engineering,
Sakarya University
, Sakarya, Turkiye
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Semanur Yildiz
;
Semanur Yildiz
Assistant Professor, Department of Food Engineering, Faculty of Engineering,
Sakarya University
, Sakarya, Turkiye
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Zehra Ayhan
Professor, Department of Food Engineering, Faculty of Engineering,
Sakarya University
, Sakarya, Turkiye
Corresponding author Zehra Ayhan (zehraayhan@sakarya.edu.tr)
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Corresponding author Zehra Ayhan (zehraayhan@sakarya.edu.tr)
Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.
Publisher: Emerald Publishing
Received:
July 19 2024
Accepted:
October 10 2024
Online ISSN: 2049-1239
Print ISSN: 2049-1220
© 2025 Emerald Publishing Limited
2025
Emerald Publishing Limited
Licensed re-use rights only
Green Materials (2025) 13 (5): 607–615.
Article history
Received:
July 19 2024
Accepted:
October 10 2024
Citation
Ara I, Haskaraca G, Yildiz S, Ayhan Z (2025), "Composite PLA films incorporated with micro/nano boron nitride for sustainable food packaging". Green Materials, Vol. 13 No. 5 pp. 607–615, doi: https://doi.org/10.1680/jgrma.24.00109
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