Formacell lignin derived from oil palm empty fruit bunches (OPEFBs) holds significant potential as a raw material for various industrial applications. However, its properties need enhancement for specific uses. This study investigated the influence of the potassium hydroxide concentration on the physicochemical properties of lignin extracted from the black liquor of OPEFBs. The chemical structure and functional groups were analyzed using pyrolysis-gas chromatography–mass spectrometry and Fourier transform infrared spectroscopy. Lignin was extracted via alkaline precipitation using potassium hydroxide (KOH) at concentrations of 5%–30%. The results indicate yields ranging from 3.57% to 14.95% on the basis of potassium hydroxide concentration. Increasing the potassium hydroxide concentration, increased lignin yields and decreased acid-insoluble lignin content. Thermogravimetric analysis demonstrated that lignin exhibited thermal stability, with degradation occurring between 100°C and 750°C. These findings suggest that lignin extraction via potassium hydroxide is an effective method for obtaining thermally stable lignin suitable for biopolymers and wood composites. However, further studies are needed to optimize the process, assess scalability, and evaluate environmental impacts. This research provides insight into improving lignin extraction techniques, enhancing its potential for sustainable industrial applications.
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Research Article|
October 02 2025
Characteristics of formacell OPEFB lignin by potassium hydroxide precipitation Available to Purchase
Sri Hidayati
;
Sri Hidayati
Department of Agricultural Product Technology,
Lampung University
, Lampung, Indonesia
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Muhammad Irfan Bakhsi
;
Muhammad Irfan Bakhsi
Research Center for Biomass and Bioproducts, Research Organization for Life Sciences and Environment,
National Research and Innovation Agency (BRIN)
, Cibinong, Indonesia
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Maya Ismayati
;
Maya Ismayati
Research Center for Biomass and Bioproducts, Research Organization for Life Sciences and Environment,
National Research and Innovation Agency (BRIN)
, Cibinong, Indonesia
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Azizatul Karimah
;
Azizatul Karimah
Research Center for Biomass and Bioproducts, Research Organization for Life Sciences and Environment,
National Research and Innovation Agency (BRIN)
, Cibinong, Indonesia
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Nissa Nurfajrin Solihat
;
Nissa Nurfajrin Solihat
Research Center for Biomass and Bioproducts, Research Organization for Life Sciences and Environment,
National Research and Innovation Agency (BRIN)
, Cibinong, Indonesia
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Antonio Di Martino
;
Antonio Di Martino
Research Center for Biomass and Bioproducts, Research Organization for Life Sciences and Environment,
National Research and Innovation Agency (BRIN)
, Cibinong, Indonesia
; Research School in Chemistry and Applied Biomedical Technologies, Tomsk Polytechnic University, Tomsk, Russian Federation
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Seng Hua Lee
;
Seng Hua Lee
Department of Wood Industry, Faculty of Applied Sciences,
Universiti Teknologi MARA Pahang Branch Jengka Campus
, Pahang, Malaysia
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Apri Heri Iswanto
;
Apri Heri Iswanto
Department of Forest Products, Faculty of Forestry,
Universitas Sumatera Utara
, Medan, Indonesia
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Puji Rahmawati Nurcahyani
;
Puji Rahmawati Nurcahyani
Food Technology Study Program, Faculty of Engineering and Industrial Education,
Universitas Pendidikan Indonesia
, Bandung, Indonesia
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Widya Fatriasari
Research Center for Biomass and Bioproducts, Research Organization for Nanotechnology and Materials,
National Research and Innovation Agency (BRIN)
, Serpong, Indonesia
Corresponding author Widya Fatriasari (widy003@brin.go.id)
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Corresponding author Widya Fatriasari (widy003@brin.go.id)
Publisher: Emerald Publishing
Received:
February 18 2025
Accepted:
July 29 2025
Online ISSN: 2049-1239
Print ISSN: 2049-1220
Funding
Funding Group:
- Award Group:
- Funder(s): National Research and Innovation Agency-BRIN
- Award Id(s): 116/II/HK/2024
- Funder(s):
- Award Group:
- Funder(s): Research Organization for Nanotechnology and Materials National Research and Innovation Agency (BRIN) FY 2025
- Award Id(s): 17/III.10/HK/2025
- Funder(s):
- Funding Statement(s): The authors are grateful for the postdoctoral program of the National Research and Innovation Agency-BRIN (Grant No. 116/II/HK/2024) for Dr. Muhammad Irfan Baksi. This study was funded by the Joint Collaboration Program of the Research Organization for Nanotechnology and Materials National Research and Innovation Agency (BRIN) FY 2025 with contract number 17/III.10/HK/2025 entitled Sintesis Nanolignin-Phosporus sebagai Filler Perekat Rendah Emisi dan Potensinya sebagai Aditif Tahan api.
© 2025 Emerald Publishing Limited
2025
Emerald Publishing Limited
Licensed re-use rights only
Green Materials (2025)
Article history
Received:
February 18 2025
Accepted:
July 29 2025
Citation
Hidayati S, Bakhsi MI, Ismayati M, Karimah A, Solihat NN, Martino AD, Lee SH, Iswanto AH, Nurcahyani PR, Fatriasari W (2025;), "Characteristics of formacell OPEFB lignin by potassium hydroxide precipitation". Green Materials, Vol. ahead-of-print No. ahead-of-print. https://doi.org/10.1680/jgrma.25.00037
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