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Novel ultra-high-performance concretes (UHPCs) made with calcium-oxide-activated materials (CAM), modified synthetic macro (MSM) fibres, glass fibres and steel fibres were developed. The mechanical and durability properties of UHPC-CAM specimens made with the different fibre types were tested and compared. The microstructure of the samples was examined using scanning electron microscopy (SEM). The environmental impacts of the mix designs were assessed using the Impact 2002+ method, a life cycle assessment tool. The results showed that the UHPC-CAM made with glass or MSM fibres had a high compressive strength (>110 MPa) and improved ductility. These specimens also had low water absorption and high electrical resistance, indicating low corrosion risk. SEM analyses showed that the MSM fibres created a denser geopolymer matrix than the glass fibres. The UHPC-CAM was found to have a lower environmental impact than conventional UHPC in terms of human health, ecosystem quality, carbon dioxide footprint and use of resources. MSM fibres were determined to be the most eco-friendly fibres for UHPC-CAM production.

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