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The influence of various supplementary cementitious materials (SCMs) and fibres on the fire resistance of composite systems that combine engineered cementitious composites (ECCs) in tension with self-compacting concrete (SCC) in compression was examined. The study was designed to determine the ideal ECC formulation for optimising mechanical properties and bonding performance at ambient and elevated temperatures. The SCC and ECC were hot-joined without vibration or surface preparation, using a fresh-to-fresh casting method. Modifications to the chemical composition of the ECCs included the addition of class F fly ash (FAF), class C fly ash (FAC) or slag, as well as polyvinyl alcohol (PVA) fibres or steel fibres. The samples were exposed to temperatures of 200°C, 400°C, 600°C and 800°C, followed by comprehensive testing to evaluate their flexural strength, tensile strength and interfacial properties. The results indicate that the incorporation of an ECC layer within the SCC system significantly improved mechanical strength and thermal stability, both at ambient temperatures and under high-temperature conditions. Notably, the addition of FAF (rather than FAC or slag) in the ECC layer offered superior thermal stability and ensured the retention of desirable residual mechanical properties. Moreover, steel fibre reinforcement greatly improved the SCC/ECC bonding, outperforming PVA reinforcement at elevated temperatures.

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