In this study, the plastic viscosity and yield stress of cement-based grouts containing n-ZnO nanoparticle added fly ash have been experimentally investigated. The fly ash ratios of the prepared grouts are 5%, 10%, 15%, 20%, 25%, and 30% by mass. The n-ZnO nanoparticles ratios in each fly ash concentration are 0.3%, 0.6%, 0.9%, 1.2%, and 1.5%. In this study, w/b ratio was selected as 1.0 because of that observing the effects of higher w/b ratios on the rheological properties of grout mixes. Ultrasonication method was applied to minimize n-ZnO precipitation in free water and to provide homogeneous dispersion in water by removing these adhering nano powders from each other. Test results showed that as the dilatant (shear-thickening) behavior was observed in all grout samples prepared for this study, modified Bingham analytical model was used to describe the rheological properties and flow behavior of the grout samples prepared for this study. n-ZnO appears to have a significant effect on regulating the amount of water required for cement-based grouts. The substitution of fly ash together with n-ZnO in grout mixtures causes the plastic viscosity values of the samples to decrease. The exponential increase is observed for the yield stress of the grout mixtures with respect to the increase in the n-ZnO additive ratio. Moreover, the increase in the fly ash amount in all n-ZnO additives causes the yield stress values of the mixtures to decrease. In addition to all, the developed artificial neural network model can predict the plastic viscosity and yield stress values of cement-based grouts containing n-ZnO nanoparticle added fly ash with average error rates of −0.52% and −0.31%, respectively.
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1 September 2025
Research Article|
November 10 2025
Some experimental evaluations on the rheological and non-Newtonian fluidity properties of fly ash added cement-based grout prepared by addition of nano zinc oxide (n-ZnO) Available to Purchase
Fatih Çelik;
Fatih Çelik
Civil Engineering Department,
Niğde Ömer Halisdemir University
, Niğde, Türkiye
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Oğuzhan Yıldız;
Oğuzhan Yıldız
Electric and Energy Department,
Niğde Ömer Halisdemir University
, Niğde, Türkiye
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Andaç Batur Çolak;
Information Technologies Application and Research Center,
Istanbul Ticaret University
, İstanbul, Türkiye
Corresponding author Andaç Batur Çolak (abcolak@ticaret.edu.tr)
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Samet Mufit Bozkır
Samet Mufit Bozkır
Civil Engineering Department,
Niğde Ömer Halisdemir University
, Niğde, Türkiye
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Corresponding author Andaç Batur Çolak (abcolak@ticaret.edu.tr)
Publisher: Emerald Publishing
Received:
September 17 2023
Accepted:
July 31 2025
Online ISSN: 2045-984X
Print ISSN: 2045-9831
Funding
Funding Group:
- Award Group:
- Funder(s): The Scientific and Technological Research Council of Turkey-TUBITAK
- Award Id(s): 219M522
- Funder(s):
- Funding Statement(s): This study was funded by The Scientific and Technological Research Council of Turkey-TUBITAK (Grant No. 219M522). The authors would like to thank TUBITAK for its great support.
© 2025 Emerald Publishing Limited
2025
Emerald Publishing Limited
Licensed re-use rights only
Nanomaterials and Energy (2025) 14 (3): 155–169.
Article history
Received:
September 17 2023
Accepted:
July 31 2025
Citation
Çelik F, Yıldız O, Çolak AB, Bozkır SM (2025), "Some experimental evaluations on the rheological and non-Newtonian fluidity properties of fly ash added cement-based grout prepared by addition of nano zinc oxide (n-ZnO)". Nanomaterials and Energy, Vol. 14 No. 3 pp. 155–169, doi: https://doi.org/10.1680/jnaen.23.00102
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