Considering the desirable attributes of nanosheets of molybdenum disulfide (MoS2) and reduced graphene oxide (RGO), the authors prepared composites of the two and investigated their use in supercapacitors. The best results were obtained with the MoS2:RGO (1:2) composite, which exhibited a specific capacitance of 416 F/g at 5 mV/s. They also studied the oxygen reduction reaction (ORR) activity of MoS2–RGO composites. Among the MoS2–RGO nanocomposites, the 1:2 composite showed the best ORR activity, since the attributes for a good supercapacitor performance are reported for this property as well. The excellent performance of the MoS2–RGO (1:2) composite is attributed to the combined effect of the good electrical conductivity of RGO and the unique surface properties of MoS2 as well as of RGO. This study indicates that good supercapacitor performance and ORR activity are governed by common factors.
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June 2015
Research Article|
June 01 2015
Performance of MoS2-reduced graphene oxide nanocomposites in supercapacitors and in oxygen reduction reaction Available to Purchase
K. Gopalakrishnan, MS;
K. Gopalakrishnan, MS
Chemistry and Physics of Materials Unit, International Centre for Materials Science, CSIR Centre of Excellence in Chemistry and Sheik Saqr Laboratory, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bangalore, India
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K. Pramoda, MS;
K. Pramoda, MS
New Chemistry Unit, International Centre for Materials Science, CSIR Centre of Excellence in Chemistry and Sheik Saqr Laboratory, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bangalore, India
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U. Maitra, PhD;
U. Maitra, PhD
Chemistry and Physics of Materials Unit, International Centre for Materials Science, CSIR Centre of Excellence in Chemistry and Sheik Saqr Laboratory, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bangalore, India
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U. Mahima, BS;
U. Mahima, BS
Chemistry and Physics of Materials Unit, International Centre for Materials Science, CSIR Centre of Excellence in Chemistry and Sheik Saqr Laboratory, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bangalore, India
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M. A. Shah, PhD;
M. A. Shah, PhD
Chemistry and Physics of Materials Unit, International Centre for Materials Science, CSIR Centre of Excellence in Chemistry and Sheik Saqr Laboratory, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bangalore, India
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C. N. R. Rao, FRS
C. N. R. Rao, FRS
*
Chemistry and Physics of Materials Unit, New Chemistry Unit, International Centre for Materials Science, CSIR Centre of Excellence in Chemistry and Sheik Saqr Laboratory, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bangalore, India
*Corresponding author e-mail address: cnrrao@jncasr.ac.in
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*Corresponding author e-mail address: cnrrao@jncasr.ac.in
Publisher: Emerald Publishing
Received:
October 12 2014
Accepted:
November 18 2014
Online ISSN: 2045-984X
Print ISSN: 2045-9831
ICE Publishing: All rights reserved
2015
Nanomaterials and Energy (2015) 4 (1): 9–17.
Article history
Received:
October 12 2014
Accepted:
November 18 2014
Citation
Gopalakrishnan K, Pramoda K, Maitra U, Mahima U, Shah MA, Rao CNR (2015), "Performance of MoS2-reduced graphene oxide nanocomposites in supercapacitors and in oxygen reduction reaction". Nanomaterials and Energy, Vol. 4 No. 1 pp. 9–17, doi: https://doi.org/10.1680/nme.14.00024
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