Solid–liquid interface energy is usually defined as the reversible work required to form or stretch plastically the solid–liquid interface per unit area. Many important processes and phenomena are directly related to it. Therefore, it is necessary to determine quantitatively the energy value of the solid–liquid interface. However, compared with the liquid–gas interface energy, it is not easy to measure the solid–liquid interface energy directly through experiments even for pure substances, and it will be more difficult to measure. Therefore, it is very necessary to develop reliable theoretical methods for predicting the solid–liquid interface energy. In this paper, an analytical model for calculating the solid–liquid interface energy of bulk materials is established. This model has no adjustable free parameters. It is obtained by combining the Gibbs–Thomson expression of the free energy at the interface between the crystal and liquid and the theory of homogeneous nucleation. The comparison with experimental data and other theoretical results verifies the correctness of the model in predicting the solid–liquid interface of metals and organic substances.
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27 June 2019
Research Article|
June 17 2019
The solid–liquid interface energy at the melting temperature of metal materials Available to Purchase
Shuai Zhang
College of Materials Science and Engineering, Jilin Jianzhu University, Changchun, China
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Publisher: Emerald Publishing
Received:
January 03 2019
Accepted:
April 01 2019
Online ISSN: 2045-984X
Print ISSN: 2045-9831
ICE Publishing: All rights reserved
2019
Nanomaterials and Energy (2019) 8 (1): 107–113.
Article history
Received:
January 03 2019
Accepted:
April 01 2019
Citation
Zhang S (2019), "The solid–liquid interface energy at the melting temperature of metal materials". Nanomaterials and Energy, Vol. 8 No. 1 pp. 107–113, doi: https://doi.org/10.1680/jnaen.19.00005
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