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Studies on the surface modification of sodium‐aluminium silicate P‐820 using silane coupling agents are described. The best modifiers were selected, which induced a change of the silicate surface from hydrophilic to hydrophobic. Physicochemical analyses of the modified silicate were performed. The methods of evaluating silicate surface modification degree were presented. The degree of hydrophobization of silicate surface was determined by a calorimetric method. Near infra‐red spectroscopy (NIR) was used to determine the degree of condensation of the silicate surface silanol groups. Studies on morphology and microstructure using transmission electron microscopy (TEM) were performed. Attempts were made to apply the unmodified and modified sodium‐aluminium silicate P‐820 as filler and pigment in silicate and dispersion paints.

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