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A series of polymeric surfactants based on butylacrylates (M1) as hydrophobe, and amide oxime of oxypropylated acrylates (M2‐4 and 6) as hydrophiles, were prepared by copolymerization of butyl acrylate (M1) and amide oxime of oxypropylated acrylate (M2‐4 and 6) with different molar ratios in presence of benzoyl peroxide as initiator to afford [(P2), (P4) and P6)]a‐i, respectively as nonionic copolymeric surfactants, in suitable yield. These derivatives were purified and characterized by microanalysis, IR and 1H NMR spectral studies. Surface active properties, corrosion inhibitions and biodegradability were evaluated.

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