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Four different organic systems, containing either vinyl acetate resins or epoxy resins were applied on steel pretreated specimens exposed to deionized and deaerated water taken from the installations of the Public Greek Electricity Company. Electrochemical Impedance Spectroscopy, potentiodynamic polarization measurements, dielectric measurements and visual observations after salt spray test were performed for monitoring the changes of the organic systems characteristics at predetermined exposure time in the deionized – deaerated water. All four coating systems found providing protection on steel surfaces. The classification of their performance depends mainly on the composition of the primer, as well as, on the intrinsic characteristics of the other layers. Thus the system consisting of epoxy primer with zinc dust, epoxy high build layer and a two component epoxy paint with iron oxide is the one exhibiting the highest protection efficiency.

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