Synthesis and characterization of Cu (II) complexes with some thiazole dye derivatives and its application in corrosion inhibition

Cu(II) complexes with some hydroxy azo compounds derived from thiazole and benzothiazole have been synthesized. The structures of the complexes are inferred from data of elemental analysis, electronic, IR and H¹ NMR spectra. It is found that the Cu(II) coordinated to ligands through the nitrogen atom of azo group and hetero ring. This coordination lead to lower the energy of CT transition of ligands. The effect of molecular structure of the ligands and nature of the metal ion on complex formation are also examined. The free energy and stability constant of complexes formed in solution have been determined spectrophotometrically. Thiazole azo dyes were found to behave as an inhibitor with respect to the corrosion of copper in acidic solutions.