The flammability of poly-acrylate (PA) resin is a major disadvantage in applications that require flame resistance. It has been reported that a flame-retardant PA resin could be prepared by covalent incorporate phosphorous containing monomer with vinyl group via free radical polymerization, and the prepared modified PA resin is expected to exhibit better flame resistance than those by an additive approach. However, the phosphorus-containing monomers reported previously are made from expensive or toxic materials, and the production procedure is tedious and under harsh reaction conditions, which are not feasible for industrial application. Therefore, the purpose of this paper is the preparation of flame-retardant PA resin modified by epoxy resin phosphorous acid (EPPA) and the study of its flame retardancy.
EPPA is first prepared by epoxy resin E-51 and phosphorous acid and then used to prepare phosphorous containing PA resin by free radical polymerization. The flame retardancy of the prepared EPPA-modified PA (EPPA-PA) resin is studied.
The results show that EPPA can graft onto the PA polymer chain by free radical polymerization, the flame retardancy of the EPPA-PA resin increases as the EPPA content increasing. The flame retardancy of EPPA-PA resin prepared reaches 27.8% and can pass the V-0 rating in the UL-94 test when EPPA content is 30.0%. SEM and EDS results indicate that phosphorous element in the EPPA-PA resin shows a condensed-phase flame retardant effect.
The grafting degree of EPPA cannot be accurately tested.
It is expected that the large-scale production of this epoxy resin phosphoric acid modified PA resin will enable practical industrial applications.
This method for synthesis of epoxy resin phosphoric acid modified PA resin is newfrangled.
