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Purpose

The purpose of this study is to evaluate the corrosion retardation properties of methylene blue on carbon steel in hydrochloric acid solutions.

Design/methodology/approach

The corrosion inhibition property of methylene blue on carbon steel was investigated by hydrogen evolution technique (gasometric technique) and weight loss measurements at 303 K and 333 K in hydrochloric acid solutions.

Findings

The results revealed that methylene blue inhibited the corrosion carbon steel, and the inhibition efficiency was temperature dependent. The maximum inhibition efficiencies were 88% at 303 K and 79.2% at 333 K. The corrosion data was consistent with the Langmuir adsorption isotherm which posits that the methylene blue molecules adhered to the metal substrate. The corrosion kinetics followed the first-order kinetic reaction equation. The activation energy (Ea) values ranged from 45.6 to 81.7 kJ/mol and indicated physical adsorption.

Originality/value

This paper provides new information on the possible application of methylene blue as corrosion inhibitor for carbon steel.

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