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Purpose

The purpose of this paper is to present the dependence of capacitive sensing of organic vapours by porous silicon (PS) on its molecular structure for the realization of a organic vapour sensor, compatible with existing silicon technology, with desired miniaturization and selectivity.

Design/methodology/approach

The method introduces large surface area of PS obtained by electrochemically etching of silicon wafer for characterization of organic vapours through capacitive sensing.

Findings

The method provides a comparative study of sensor response for organic vapour molecules of different structures and leads to an insight into the sensing mechanism.

Research limitations/implications

The surface of PS has been stabilized by thermal oxidation process.

Practical implications

The method is useful for the development of a simple, cost‐effective sensor for selective gas analysis.

Originality/value

The result is an outcome of regular experimental work carried out to observe the capacitive sensing behavior of PS for different organic vapours.

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