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Volume 48, Issue 6
1 December 2001
Anti-Corrosion Methods and Materials Cover Image for Volume 48, Issue 6
Editors
Yu Yan
Yu Yan
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Technical Paper| December 01 2001

Influence of sodium sulphite on corrosion inhibition by the sodium gluconate –Zn2+ system Available to Purchase

A. John Amalraj;
A. John Amalraj
The Department of Chemistry, Gandhigram Rural Institute (Deemed University), Tamil Nadu, India
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M. Sundaravadivelu;
M. Sundaravadivelu
The Department of Chemistry, Gandhigram Rural Institute (Deemed University), Tamil Nadu, India
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A. Peter Pascal Regis;
A. Peter Pascal Regis
Department of Chemistry, St Joseph’s College, Trichy, Tamil Nadu, India
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S. Rajendran
S. Rajendran
The Department of Chemistry, G.T.N. Arts College, Dindigul, Tamil Nadu, India
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Author & Article Information
Publisher: Emerald Publishing
Online ISSN: 1758-4221
Print ISSN: 0003-5599
© MCB UP Limited
2001
Anti-Corrosion Methods and Materials (2001) 48 (6): 371–375.
https://doi.org/10.1108/EUM0000000006257

The inhibition efficiency of sodium gluconate (SG) in controlling corrosion of carbon steel immersed in the environment containing 60 ppm Cl– has been evaluated in the presence and absence of Zn2+ by weight loss method. SG and Zn2+ show a synergistic effect. The protective film has been analysed by FTIR and fluorescence spectra. The protective film consists of Fe2+‐gluconate complex and Zn(OH)2. The film is found to be UV‐fluorescent. The IE of the SG‐Zn2+ system increases in the presence of Na2SO4; but decreases in the presence of Na2SO3 and also in the presence of N‐cetyl‐N,N,N‐trimethyl ammonium bromide. This study reveals that the transporting phenomenon plays a larger role than the scavenging of dissolved oxygen.

Keywords:
Corrosion prevention, Steel
© MCB UP Limited
2001
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