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Accuracy of hydrodynamic transport equations using the energy‐dependent relaxation times has been studied for electron transport in Si 〈100〉. The concept of the hydro‐kinetic transport model is used to describe non‐equilibrium electron transport phenomena and to examine the validity for the assumption of energy‐dependent relaxation times. It has been shown that under the influence of a drastic increase in field the relaxation times might also strongly depend on the average velocity near the peak of strong velocity overshoot. In addition, the velocity dependence is found to be more pronounced at lower temperatures in Si 〈100〉.

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