Composite fibers were prepared by homogeneous dispersion of nanomagnetite (NM) in the ionic liquid 1-ethyl-3-methylimidazolium acetate ([C2mim]OAc) using ultrasonication followed by dissolution of microcrystalline cellulose at 90°C and dry-jet wet spinning into a water coagulation bath. The processing method with specific successive steps regarding the addition of the components has a large influence on the quality of dispersion and thus the mechanical properties of the fibers. A nanomagnetite load of up to 0.75% (mass ratio expressed in percent of nanomagnetite to cellulose) in the cellulose matrix results in significantly improved mechanical properties of the fibers, while at loads higher than 1% NM, the ultimate stress and modulus of the fibers are lower because of the formation of large agglomerates that create defects within the fibers. Fibers with uniform diameter and better reproducibility of mechanical properties can be produced utilizing high-performance equipment for fiber processing.
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July 2012
Review Article|
July 01 2012
Reinforced magnetic cellulose fiber from ionic liquid solution Available to Purchase
Mirela L. Maxim, MS, CGM Chem UA;
Mirela L. Maxim, MS, CGM Chem UA
Graduate student
Center for Green Manufacturing and Department of Chemistry, The University of Alabama, Tuscaloosa, AL, USA
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Ning Sun, PhD, CGM Chem UA;
Ning Sun, PhD, CGM Chem UA
Center for Green Manufacturing and Department of Chemistry, The University of Alabama, Tuscaloosa, AL, USA
Current affiliation: Postdoctoral Researcher at Joint BioEnergy Institute Lawrence Berkeley National Laboratory
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Hui Wang, PhD, CGM Chem UA;
Hui Wang, PhD, CGM Chem UA
Postdoctoral fellow
Center for Green Manufacturing and Department of Chemistry, The University of Alabama, Tuscaloosa, AL, USA
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Joseph R. Sterner, BS, AEM UA;
Joseph R. Sterner, BS, AEM UA
Undergraduate student
Department of Aerospace Engineering and Mechanics, The University of Alabama, Tuscaloosa, AL, USA
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Anwarul Haque, PhD, AEM UA;
Anwarul Haque, PhD, AEM UA
Associate Professor
Department of Aerospace Engineering and Mechanics, The University of Alabama, Tuscaloosa, AL, USA
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Robin D. Rogers, PhD, Chem CGM CG&D
Robin D. Rogers, PhD, Chem CGM CG&D
*
Robert Ramsay Chair of Chemistry
Center for Green Manufacturing and Department of Chemistry, The University of Alabama, Tuscaloosa, AL, USA
*Corresponding author email address: RDRogers@as.ua.edu
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*Corresponding author email address: RDRogers@as.ua.edu
Publisher: Emerald Publishing
Received:
March 21 2012
Accepted:
May 15 2012
Online ISSN: 2045-984X
Print ISSN: 2045-9831
ICE Publishing: All rights reserved
2012
Nanomaterials and Energy (2012) 1 (4): 225–236.
Article history
Received:
March 21 2012
Accepted:
May 15 2012
Citation
Maxim ML, Sun N, Wang H, Sterner JR, Haque A, Rogers RD (2012), "Reinforced magnetic cellulose fiber from ionic liquid solution". Nanomaterials and Energy, Vol. 1 No. 4 pp. 225–236, doi: https://doi.org/10.1680/nme.12.00010
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