Acrylic modified water soluble oil based coatings

Acryclic copolymers from methacrylic acid‐ethyl acrylate or butylacrylate were prepared and incorporated into the castor oil alkyd structure. The neutralised product was water soluble. Water soluble hexamethoxy methyl melamine resin was prepared and used as curing agent. Several proportions of water soluble acrylic modified alkyds and hexamethoxy methyl melamine resin were examined at various baking schedules. It was established that 30% of the curing agent gave most satisfactory properties after baking at 150°C for 30 minutes. It was found that ethyl acrylate modified compositions had better scratch hardness and acid resistance than those of the butyl acrylate modified composition. However, the latter had better alkali resistance. These surface coating compositions have been recommended as industrial primers.