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Purpose

This paper aims to report the conductivity measurement of ten different surfactant-free microemulsions (SFMEs)

Design/methodology/approach

The variations of electrical conductivity as a function of water volume fraction are examined at one constant alcohol (or DMF, ethyl lactate, γ-valerolactone)/water, alcohol (or DMF, ethyl lactate, γ-valerolactone)/oil volume ratios for each sample.

Findings

Most of the results are consistent with percolation character. The conductive mechanism of these SFMEs is discussed by the percolation model, and it is found that it might be described with the static percolation model below the percolation threshold.

Originality/value

Our report gives a systematic research on the percolation mechanism of as many species of SFMEs as possible by the theoretical models

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